This catalogue is not the official APVMA website or PubCRIS register. The approved label is the legal authority.

NUFARM ASSOCIATE HERBICIDE — label 47737

Original approved APVMA PDF

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Product Name:          NUFARM ASSOCIATE HERBICIDE
APVMA Approval No:     46361/140531
                                                                                                                         RLP
                                                                                                                        APPROVED




Label Name:            NUFARM ASSOCIATE HERBICIDE



Signal Headings:       READ SAFETY DIRECTIONS BEFORE OPENING OR USING



Constituent            ACTIVE CONSTITUENT: 600 g/kg METSULFURON-METHYL
Statements:



Mode of Action:
                         GROUP          2     HERBICIDE




Statement of Claims:   For control of certain brush and broadleaf weed species in native pastures, rights of way
                       and commercial and industrial areas and for the control of certain broadleaf weeds in winter
                       cereal crops, grass pastures and pasture renovation as per the DIRECTIONS FOR USE.



Net Contents:          100 g - 500 g



Restraints:            RESTRAINTS
                       DO NOT store a suspension of Nufarm Associate® for more than two days otherwise
                       significant breakdown will occur.
                       DO NOT apply to crops under stress.
                       DO NOT store tank mixes of Nufarm Associate®.
                       DO NOT apply if rainfall is expected within 2 hours (for woody weeds 4 hours).
                       DO NOT use on furrow or flood irrigated crops.
                       DO NOT apply before the three leaf stage of the crop when used for post emergent weed
                       control.
                       DO NOT treat newly sown pastures as severe damage may occur.
                       DO NOT use on pasture seed crops.
                       DO NOT apply to weeds that are under stress or not actively growing.

                       DO NOT use in winter cereal crops under sown with legume pasture species, e.g. medics, clovers

                       Spray Drift Restraints
                       Specific definitions for terms used in this section of the label can be found at apvma.gov.au/
                       spraydrift.
                       DO NOT allow bystanders to come into contact with the spray cloud.
                       DO NOT apply in a manner that may cause an unacceptable impact to native vegetation,
                       agricultural crops, landscaped gardens and aquaculture production, or cause contamination
                       of plant or livestock commodities, outside the application site from spray drift. Wherever

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possible, correctly use application equipment designed to reduce spray drift and apply
                        when the wind direction is away from these sensitive areas.
                        DO NOT apply unless the wind speed is between 3 and 20 kilometres per hour at the
                        application site during the time of application.
                        DO NOT apply if there are hazardous surface temperature inversion conditions present at
                        the application site during the time of application. Surface temperature inversion conditions
                        exist most evenings 1 to 2 hours before sunset and persist until 1 to 2 hours after sunrise.



Directions for Use:     This section contains file attachment.




Other Limitations:




                        WITHHOLDING PERIODS
Withholding Periods:    CEREALS NUFARM ASSOCIATE® ONLY - NOT REQUIRED WHEN USED AS
                        DIRECTED.
                        CEREALS NUFARM ASSOCIATE® MIXTURES:
                        - TANK MIXES NUFARM AGTRYNE, NUFARM MCPA AMINE 750, NUFARM 2,4-D
                        AMINE 625, TIGREX, TORDON 242 OR NUFARM IGRAN 500 – DO NOT GRAZE OR
                        CUT FOR STOCK FOOD FOR 7 DAYS AFTER APPLICATION.
                        - TANK MIXES WITH NUFARM BROMICIDE® MA – DO NOT GRAZE OR CUT FOR
                        STOCK FOOD FOR 14 DAYS AFTER APPLICATION.
                        CHICKPEAS TANK MIXES WITH NUFARM CRUCIAL® OR NUFARM WEEDMASTER®
                        DST®:
                        - DO NOT HARVEST FOR 7 DAYS AFTER APPLICATION
                        - DO NOT GRAZE OR CUT FOR STOCK FOOD FOR 7 DAYS AFTER APPLICATION
                        PASTURES AND OTHER USE SITUATIONS – NOT REQUIRED WHEN USED AS
                        DIRECTED.
                        WHEN APPLYING WITH OTHER TANK-MIX PRODUCTS, OBSERVE THE HARVEST
                        AND GRAZING WITHHOLDING PERIOD FOR THE TANK MIX PRODUCT


Trade Advice:


General Instructions:
                        This section contains file attachment.




Resistance Warning:     RESISTANT WEEDS WARNING

                        GROUP 2 HERBICIDE

                        Nufarm Associate® Herbicide is a member of the Sulfonylurea group of herbicides. Nufarm
                        Associate® has the inhibitors of acetolactate synthase mode of action. For weed resistance
                        management Nufarm Associate® is a Group 2 herbicide. Some naturally-occurring weed
                        biotypes resistant to Nufarm Associate® and other Group 2 herbicides may exist through
                        normal genetic variability in any weed population. The resistant individuals can eventually
                        dominate the weed population if these herbicides are used repeatedly. These resistant
                        weeds will not be controlled by Nufarm Associate® or other Group 2 herbicides. Some
                        populations of Annual Ryegrass and a few broadleaf weeds are already known to be

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resistant to Nufarm Associate® and other ALS inhibitor herbicides. Since the occurrence
                     of resistant weeds is difficult to detect prior to use, Nufarm Australia Limited accepts no
                     liability for any losses that may result from the failure of Nufarm Associate® to control
                     resistant weeds. To prevent, or at least minimise the risk of resistant weeds occurring, use
                     Nufarm Associate® in tank mixes (if appropriate) and/or rotations with herbicides having
                     different modes of action effective on the same weed species. Large numbers of healthy
                     surviving weeds can be an indication that resistance is developing. Efforts should be taken
                     to prevent seed set of these survivors.
                     DO NOT apply Nufarm Associate® alone for fallow and preplant knockdown weed control.
                     DO NOT make more than one application of an ALS inhibitor herbicide to a crop, either
                     preplant, incorporated-by-sowing or post crop and weed emergence. If the user suspects
                     that an ALS inhibitor resistant weed is present, Nufarm Associate® or other ALS inhibitor
                     herbicides should not be used. Strategies to minimise the risk of herbicide resistance are
                     available. Consult your farm chemical supplier, consultant, local Department of Agriculture
                     or Primary Industries, or local Nufarm representative.



Precautions:



Protections:         PROTECTION OF CROPS, NATIVE AND OTHER NON-TARGET PLANTS
                     Injury to or loss of desirable trees or vegetation may result from failure to observe the
                     following:
                     DO NOT apply or drain or flush equipment on or near desirable trees or other plants or on
                     areas where their roots may extend or in locations where the chemical may be washed or
                     moved into contact with their roots.
                     DO NOT apply or allow spray to drift onto adjacent crops and non-target desirable plants,
                     or onto agricultural land scheduled to be planted to other crops as injury to the crop may
                     occur.

                     PROTECTION OF LIVESTOCK
                     A nil grazing withholding period is applicable for Nufarm Associate® following application to
                     pastures. It is recommended, however, not to graze treated areas for 2 to 3 days to ensure
                     product efficacy.

                     PROTECTION OF WILDLIFE, FISH, CRUSTACEANS AND ENVIRONMENT
                     DO NOT contaminate streams, rivers or watercourses with the chemical or the used
                     containers.



Storage and          STORAGE AND DISPOSAL
Disposal:            KEEP OUT OF REACH OF CHILDREN.
                     Store in the closed, original container in a cool, well-ventilated area. DO NOT store for
                     prolonged periods in direct sunlight.
                     Triple-rinse containers before disposal. Add rinsings to spray tank. DO NOT dispose of
                     undiluted chemicals on site. If recycling, replace cap and return clean containers to recycler
                     or designated collection point. If not recycling, break, crush, or puncture and deliver empty
                     packaging to an approved waste management facility. If an approved waste management
                     facility is not available, bury the empty packaging 500 mm below the surface in a disposal
                     pit specifically marked and set up for this purpose, clear of waterways, desirable vegetation
                     and tree roots, in compliance with relevant local, state or territory government regulations.
                     DO NOT burn empty containers or product.



Safety Directions:   SAFETY DIRECTIONS

                     Harmful if swallowed. Will irritate the eyes and skin. Avoid contact with eyes and skin.
                     When opening the container and preparing spray wear elbow-length Chemical resistant
                     gloves and goggles. If applying by hand wear cotton overalls, over normal clothing,
                     buttoned to the neck and wrist, a washable hat, and elbow-length Chemical resistant

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gloves. If product on skin, immediately wash area with soap and water. If product in eyes,
                          wash it out immediately with water. Wash hands after use. After each day’s use, wash
                          gloves, goggles and contaminated clothing.



First Aid Instructions:   FIRST AID
                          If poisoning occurs, contact a doctor or Poisons Information Centre.
                          Phone Australia 13 11 26, New Zealand 0800 764 766.



First Aid Warnings:

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Nufarm Associate Herbicide – Directions for Use
1. CEREALS: NUFARM ASSOCIATE® ONLY - POST CROP AND WEED EMERGENCE BY GROUND AND AERIAL APPLICATION
 CROP               WEEDS                                          STATE             RATE        WEED GROWTH                       CRITICAL COMMENTS
                                                                                                 STAGE
 Wheat, Barley,     African turnip weed (Sisymbrium thellungii)    All states        5 g/ha      Apply before the 6 leaf           General: Where the two rates are specified, use the
 Triticale & Cereal Amsinckia/Yellow burweed (Amsinckia spp.)      WA                            stage                             higher rate for larger weeds and/or under heavy weed
 rye                                                               All states except 5 or 7 g/ha                                   pressures.
                                                                   WA
                    Ball mustard (Neslia paniculata)               All states        5 g/ha                                        Where weed growth stage is not specified in the
                    Boggabri weed/Dwarf amaranth (Amaranthus       All states except 7 g/ha      Apply at cotyledon to             adjacent column, apply when weeds are small (ie. no
                    macrocarpus)                                   WA                            10cm height or                    greater than 5 cm in height or diameter) and actively
                                                                                                 diameter stage                    growing.
                    Calomba daisy (Pentzia suffruticosa)           All states        5 g/ha
                    Cape tulip (Homeria spp.)                                                                                      Refer to General Instructions and Crop Safety
                    Charlock (Sinapsis arvensis)                                                                                   Directions for further application instructions.
                    Chickpeas (Volunteer) (Cicer arietinum)
                    Chickweed (Stellaria media)
                    Chicory (Cichorium intybus)
                    Clover (Subterranean) (Trifolium subterraneum)
                    Common sowthistle (Sonchus oleraceus)                                        Apply up to 4 leaf
                    Cutleaf mignonette (Reseda lutea)              All states except 7 g/ha      stage                             Spray actively growing large plants, up to early
                                                                   WA                                                              flowering stage. Plants emerging after spraying may
                                                                                                                                   not be controlled.
                   Deadnettle (Lamium amplexicaule)                    All states          5 g/ha
                   Denseflower fumitory(Fumaria densiflora)            All states          5 g/ha
                   Dock (Broadleaf) (Rumex obtusifolius)               WA
                                                                       All states except   5 or 7 g/ha
                                                                       WA
                   Faba beans (Vicia faba)                             All states          5 g/ha        Apply after 3 node
                   Field peas (Pisum sativum)                                                            stage
                                                                       All states except   7 g/ha
                                                                       WA
                   Hare’s ear/Treacle mustard (Conringia orientalis)   All states          5 g/ha        Apply before 5 leaf
                                                                                                         stage
                   Hogweed/Wireweed (Polygonum aviculare)              WA                                Apply before 4 leaf
                                                                                                         stage
                                                                       All states except   5 or 7 g/ha                             Use the higher rate when weed populations are dense
                                                                       WA                                                          and majority of weeds are 4 leaf.
                   Indian hedge mustard (Sisymbrium orientale)         All states          5 g/ha                                  Heavy populations and/or those suffering cold or
                                                                                                                                   moisture stress may not be completely controlled - a
                                                                                                                                   tank mix with Nufarm MCPA LVE 570 is
                                                                                                                                   recommended.
                   Lincoln weed (Diplotaxis tenuifolia)                All states except   7 g/ha                                  Apply to actively growing plants from late Winter to
                                                                       WA                                                          Spring. Plants emerging after spraying may not be
                                                                                                                                   controlled.
                   Lupins (Lupinus albus)                              All states          5 g/ha
                   Mallee catchfly (Silene apetala)
                   Medic (Medicago spp.)
                   New Zealand spinach(Tetragonia tetragonoides)       All states except   7 g/ha        Apply before 4 leaf
                                                                       WA                                stage
                   Parthenium weed (Parthenium hysterophorus)          All states          5 g/ha        Apply up to 4 leaf
                                                                                                         stage
                                                                       All states except   7 g/ha        Apply at 4 leaf to
                                                                       WA                                rosette stage
                   Paterson’s curse/Salvation Jane (Echium             All states          5 g/ha
                   plantagineum)                                       All states except   5 or 7 g/ha
                                                                       WA
                   Prickly lettuce (Lactuca serriola)                  All states except   5 or 7 g/ha
                                                                       WA
                                                                       WA                  5 g/ha
                   Red pigweed (Portulaca oleracea)                    All states          5 g/ha        Apply before 6 leaf
                                                                                                         stage
                                                                       All states except   7 g/ha        Apply when weed
                                                                       WA                                populations are dense
                                                                                                         and majority of weeds
                                                                                                         are 6 leaf stage
                   Rough poppy (Papaver hybridum)                      All states          5 g/ha
                   Saltbush (Atriplex muelleri)                        All states          5 g/ha        Apply up to 4 leaf
                                                                                                         stage
                                                                       All states except   7 g/ha        Apply at 4-6 leaf stage
                                                                       WA
                   Shepherd’s purse (Capsella bursapastoris)           All states          5 g/ha
                   Skeleton weed (Chondrilla juncea) (Suppression      All states except   7 g/ha
                   only)                                               WA
                                                                       WA                  5 g/ha

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CROP                WEEDS                                                 STATE                  RATE          WEED GROWTH               CRITICAL COMMENTS
                                                                                                                STAGE
 Wheat, Barley,     Slender celery (Apium leptophyllum)                    All states             5 g/ha
 Triticale & Cereal Smallflower fumitory (Fumaria parviflora)
 rye,               Sorrell (Rumex acetosella)                                                                                            Some regeneration from underground rootstocks and
 cont.                                                                                                                                    new germinations may occur late in the season.
                    Soursob (Oxalis pes-caprae)                                                                                           Apply after majority of soursobs have emerged and
                                                                                                                                          are actively growing.
                     Spiny emex/Doublegee/Three-comered Jack
                     (Emex australis)                                      All states except      5 or 7 g/ha
                                                                           WA
                     Stagger weed (Stachys arvensis)                       All states             5 g/ha
                     Storksbill/Wild geranium (Erodium spp.)               All states             5 g/ha
                     Turnip weed (Rapistrum rugosum)
                     Volunteer sunflower (Helianthus annuus)               All states             5 g/ha        Apply at cotyledon to 4
                                                                                                                leaf stage.
                                                                           All states except      7 g/ha        Apply at 4 to 8 leaf
                                                                           WA                                   stage.
                     Wild/Crow garlic (Allium vineale)                     All states except      7 g/ha        Apply at 1 - 2 leaf
                                                                           WA                                   stage
                     Wild turnip (Brassica tournefortii)                   All States             5 g/ha

2. CEREALS: NUFARM ASSOCIATE® MIXTURES - POST CROP AND WEED EMERGENCE BY GROUND AND AERIAL APPLICATION
For the control of weeds in addition to those listed above the following mixtures with their appropriate timings are recommended. For mixing instructions refer to “Spray Preparation” Section.
 CROP                WEEDS                              STATE         RATE                                 CROP STAGE                        CRITICAL COMMENTS
 Wheat, Barley,      Capeweed (Arctotheca               All states 5 g/ha + 280 g/ha of a diuron WG 3 - 5 leaf (Z13-15) NSW only
 Triticale & Cereal calendula)                                        formulation + 330 mL/ha Nufarm 5 leaf (Z15) Vic only                   Some wheat varieties may be more susceptible
 rye                 Wild radish (Raphanus                            MCPA Amine 750                                                         to damage from these mixtures, consult your
                     raphanistrum)                                    5 g/ha + 280 g/ha of a diuron WG 3 - 5 leaf (Z13-15)                   local agronomist or Nufarm representative.
                                                                      formulation + 330 mL/ha Nufarm                                         Apply when weeds are 2-5 leaf.
                                                                      MCPA Amine 750
                     Volunteer canola including                       5 g/ha + 440 mL/ha Nufarm            3 - 5 leaf (Z13-15)
                     Roundup Ready® varieties                         MCPA LVE 570 (up to 4 leaf
                     (Brassica napus)                                 canola)
                                                                      5 g/ha + 880 mL/ha Nufarm
                                                                      MCPA LVE 570 (up to 6 leaf
                                                                      canola)
                     Capeweed (Arctotheca                             5 g/ha + 195 g/ha of a diuron WG 3 - 4 leaf (Z13-14)                   Apply when weeds are 2 - 5 Leaf.
                     calendula)                                       formulation + 270 mL/ha Nufarm
                     Wild radish (Raphanus                            MCPA Amine 750
 Wheat, Barley       raphanistrum)                                    5 g/ha + 550 mL/ha Nufarm            3 leaf - early tillering          Apply when weeds are 2 - 6 leaf.
                                                                      Igran® + 400 mL/ha of Nufarm         (Z13-21)
                                                                      MCPA Amine 750
                     Capeweed (Arctotheca                             5 g/ha + 550 mL/ha Nufarm
                     calendula)                                       Igran®
                                                                      5 g/ha + 850 mL/ha Nufarm
                                                                      Igran®
                                                                      5 g/ha + 1L/ha Nufarm Agtryne® 3 - 5 leaf (Z13-15)                     Spray actively growing weeds at the 2 - 6 leaf stage.
 Wheat, Barley,                                                       5 g/ha + 750 mL/ha Nufarm            3 leaf to full tillering (SA, WA  Apply when weeds are up to 6 leaf stage
 Triticale & Cereal                                                   Bromicide® MA                        only)
 Rye                                                                  5 g/ha + 1.4 L/ha Nufarm             5 leaf to full tillering (Qld,    WA - Apply when weeds are 6 - 8 leaf.
                                                                      Bromicide® MA                        NSW, Vic, Tas only)
                                                                      5 g/ha + 2.1 L/ha Nufarm             3 leaf to full tillering (SA      Apply when weeds are 6 - 8 leaf.
                                                                      Bromicide® MA                        only) 5 leaf to full tillering
                                                                                                           (Qld, NSW, Vic, Tas only)
                     Wild radish (Raphanus                            5 g/ha + 470 – 670 mL/ha             Early tillering to before boot    Apply the lower rate to seedling weeds (3 - 6 leaf)
                     raphanistrum)                                    Nufarm MCPA Amine 750                (Z21-39)                          and the higher rate on well-developed weeds up to
                                                                                                           Apply 470mL/ha rate after         rosette.
                                                                                                           crop has reached 5 leaf stage.
                                                                                                           Use higher rates after the first
                                                                                                           node can be felt at the base of
                                                                                                           the tiller and before swelling of
                                                                                                           the head can be felt in the
                                                                                                           tiller.
                                                                      5 g/ha + 930 mL/ha Nufarm            Early tillering to before boot    Apply when weeds are seedling to rosette.
                                                                      MCPA Amine 750                       (Z21-39)
                                                                      5 g/ha + 800 mL/ha Nufarm            5 leaf - tillering (Z15-30)
                                                                      MCPA Amine 750

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CROP                 WEEDS                         STATE        RATE                              CROP STAGE                         CRITICAL COMMENTS
Wheat, Barley        Wild radish (Raphanus         All states   5 g/ha + 250 mL/ha Tigrex*        Wheat: 3 leaf to late tillering    Apply up to the 4 leaf stage and not more than 10
                     raphanistrum)                                                                (Z13-30)                           cm in diameter.
                                                                                                  Barley: 5 leaf to late tillering
                                                                                                  (Z15-30)
Wheat, Barley,                                                  5 g/ha + 960 mL/ha - 1.4 L/ha     5 leaf to commencement of          Apply up to 2 - 3 leaf stage only.
Triticale & Cereal                                              Nufarm MCPA LVE 570               flag leaf (Z15-37)
rye                Saffron thistle (Carthamus                   5 g/ha + 960 mL/ha - 1.4 L/ha     5 leaf through to                  Spray young rosettes before leaves become spiny.
                   lanatus)                                     Nufarm MCPA LVE 570               commencement of flag leaf
                                                                                                  (Z15-37)
                                                                5 g/ha + 930 mL/ha- 1.4 L/ha      Early tillering to before boot     Apply to weeds at seedling to rosette stage. Use the
                                                                Nufarm MCPA Amine 750             (Z21-39). Higher rates (above      lower rate on seedling weeds and the higher rate on
                                                                                                  1L/ha of Nufarm Agritone® 750      well-developed weeds.
                                                                                                  only to be used on crops from
                                                                                                  mid tillering to before boot
                                                                                                  stage (Z23-29).
                                                                5 g/ha + 120 mL/ha Nufarm         4 - 5 leaf stage (Z14-15).         Spray when weeds are young and actively growing.
                                                                Archer®                                                              DO NOT apply Nufarm Archer® to a cereal crop if
                                                                                                                                     field peas are to be sown the following season
                                                                                                                                     unless the cereal stubble is burnt.
                     Variegated thistle                         5 g/ha + 1.2 L/ha Nufarm 2,4-D  5 leaf to early tillering            Apply to weeds at seedling to rosette stage.
                     (Silybum marianum)                         Amine 625                       (Z15-21).
                                                                5 g/ha + 700 mL/ha - 1.4 L/ha   Apply after the first node can       Apply to weeds at seedling to rosette stage. Use the
                                                                Nufarm 2,4-D Amine 625          be felt at the base of the tiller    lower rate on seedling weeds and the higher rate on
                                                                                                and before swelling of the head      well-developed weeds.
                                                                                                can be felt in the tiller.
                                                                5 g/ha + 0.9 L/ha Nufarm 2,4-D  Mid tillering to before boot         Apply to weeds at the seedling to rosette stage.
                                                                Amine 625                       (Z23-39).
                                                                5 g/ha + 1 L/ha Nufarm MCPA     Early tillering to before boot
                                                                Amine 750                       (Z21-39).
                                                                5 g/ha + 740 - 960 mL/ha Nufarm Apply from 5 leaf through to         Spray at pre-cabbage stage.
                                                                MCPA LVE 570                    commencement of flag leaf
Wheat                Slender thistle                            5 g/ha + 1.85 L/ha Nufarm MCPA (Z15-37).                             Moderately susceptible. Spray young rosettes.
                     (Carduus tenuiflorus)                      LVE 570
Wheat, Barley,                                                  5 g/ha + 0.8 - 1.4 L/ha Nufarm  Apply after the first node can       Apply to weeds at seedling to rosette stage. Use the
Triticale & Cereal                                              Amicide® 625                    be felt at the base of the tiller    lower rate on seedling weeds and the higher rate on
rye                                                                                             and before swelling of the head      well-developed weeds.
                                                                                                can be felt in the tiller.
                     Slender thistles                           5 g/ha + 1.4 L/ha Nufarm 2,4-D  5 leaf to early tillering            Apply to weeds at seedling to young rosette stage.
                     (Carduus tenuiflorus and                   Amine 625                       (Z15-21).
                     Carduus pycnocephalus)
Wheat, Barley &      Climbing Buckwheat/Black      All states 5 – 7 g/ha + 1L /ha Nufarm          Apply from early tillering (when For best control apply at early tillering as this weed
Triticale            bindweed                      except WA Picloram MCPA/ Tordon* 242           the main shoot has 4 to 5        becomes increasingly difficult to control as it
                     (Fallopia convolvulus)                                                       leaves plus 2 or more new        becomes larger.
                                                                                                  tillers have formed) to start of
                                                                                                  jointing (first node).

3. CEREALS: NUFARM ASSOCIATE® + NUFARM CRUCIAL® OR NUFARM WEEDMASTER® DST® - FALLOW/PREPLANT KNOCKDOWN WEED CONTROL
 CROP          WEEDS                       STATE      RATE                       WEED GROWTH STAGE CRITICAL COMMENTS
 Wheat         Refer to Post Crop and Weed All states Nufarm Associate® 5 or 7   Refer to Post Crop and   DO NOT apply less than 10 days prior to sowing as crop
               Emergence section of this   except WA  g/ha + Nufarm Crucial® or  Weed Emergence section injury may occur, particularly under dry, cold conditions.
               leaflet (Table 1), and the             Nufarm weedmaster® DST® of this leaflet (Table 1),  Apply when weeds are actively growing.
               Nufarm Crucial® and                    at label rates             and the Nufarm Crucial® Refer to General Instructions and Critical Comments of the
               weedmaster® DST® Directions WA only    Nufarm Associate® 5 g/ha + or Nufarm weedmaster® respective labels.
               for Use.                               Nufarm Crucial® or Nufarm DST® Directions for Use. Use the appropriate rate of each product for the target weed
                                                      weedmaster® DST® at label                           spectrum.
                                                      rates
 Barley,       Refer to Post Crop and Weed All states Nufarm Associate® 5 or 7   Refer to Post Crop and   DO NOT apply less than 6 weeks prior to sowing as crop
 Cereal        Emergence section of this   except WA  g/ha + Nufarm Crucial® or  Weed Emergence section injury may occur, particularly under dry, cold conditions.
 Rye or        leaflet (Table 1), and the             Nufarm weedmaster® DST® of this leaflet (Table 1),  Apply when weeds are actively growing. Refer to General
 Triticale     Nufarm Crucial® and                    at label rates             and the Nufarm Crucial® Instructions and Critical Comments of the respective labels.
               weedmaster® DST® Directions                                       or Nufarm weedmaster® Use the appropriate rate of each product for the target weed
               for Use.                    WA only    Nufarm Associate® 5 g/ha + DST® Directions for Use. spectrum.
                                                      Nufarm Crucial® or Nufarm
                                                      weedmaster® DST® at label
                                                      rates

4. NUFARM ASSOCIATE® + NUFARM CRUCIAL® OR NUFARM WEEDMASTER® DST® - CHICKPEA DESICCATION AND KNOCKDOWN WEED CONTROL (ALL STATES)
 CROP                               WEEDS                       RATE            WEED GROWTH STAGE            CRITICAL COMMENTS
 Chickpeas - pre-harvest            Refer to Post Crop and Weed 5 g/ha + Nufarm Refer to Post Crop and       Apply when chickpeas are physiologically mature and less than 15% of
 application as a crop desiccant    Emergence section of this   Crucial® 450 - Weed Emergence section green pods are present.
 and knockdown weed control         label (Table 1), and the    950 mL/ha or    of this label (Table 1), and Use the higher rate of Nufarm Crucial® or Nufarm weedmaster® DST®
 (Application to crops intended for Nufarm Crucial™ or Nufarm   Nufarm          the Nufarm Crucial® or       when crops or weeds are dense and where faster desiccation is
 seed production or for sprouting weedmaster® DST® directions weedmaster®       Nufarm weedmaster®           required. Speed of desiccation is dependent on crop stage, growing
 may reduce germination             for use                     DST® 580 -      DST® directions for use .    conditions and weather conditions during and after application.
 percentage to commercially                                     1200 mL/ha                                   This use should be part of an Integrated Weed Management Strategy
 unacceptable levels.)                                                                                       that incorporates herbicides with different modes of action and
                                                                                                             alternative cultural weed practices.

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5. NATIVE PASTURES, RIGHTS OF WAY, COMMERCIAL AND INDUSTRIAL AREAS - GROUND APPLICATION
 SITUATION         WEEDS                             STATE                  RATE              CRITICAL COMMENTS
                                                                Boom      Handgun Gas gun
 Native pastures¥, Alligator weed (Alternanthera     All states 80 g/ha   -         -         Apply in terrestrial situations only. Follow-up applications over at least two
 rights of way,    philoxeroides)                    except WA                                seasons are essential for complete control.
 commercial and Apple box (Angophora floribunda)                -         10 g/100L 1 g/L +   Apply to plants up to 4m high. Avoid spraying when plants are stressed.
 industrial areas  Messmate stringybark (Eucalyptus                       + Pulse®  Pulse®    Ensure thorough foliage cover. Results cannot be guaranteed where suckers
                   obliqua)                                               Penetrant Penetrant originate from large lignotubers.
                   Peppermint gum (E. radiata)                            (200mL/ (10mL/5L)
                   Red gum (E. blakelyi)                                  100L)
                   Yellow box (E. melliodora)
                   Australian blackthorn (Bursaria              -         10 g/100L -         Apply when bushes are actively growing. Avoid spraying when bushes are
                   spinosa)                                                                   stressed. Handgun - Spray to thoroughly wet all foliage, but not to cause run-
                   Bellyache bush (Jatropha                     -         10 g/100L -         off.
                   glossypifolia)                                         + Pulse®
                                                                          Penetrant
                                                                          (200 mL/
                                                                          100L)
                   Blackberry (Rubus spp.)           All states -         10 g/100L 1 g/L +   Apply when bushes are actively growing; (Tas only: Apply after petal fall.) (Vic
                                                                          +         Pulse®    only: Apply between December and April). Spray to thoroughly wet all foliage
                                                                          mineral   Penetrant and canes. Ensure peripheral runners are sprayed. In Tasmania, DO NOT
                                                                          crop oil  (10mL/5L) apply to bushes carrying mature fruit.
                                                                          (1L/100L)
                   Bitou bush/Boneseed               All states -         10 g/100L 1 g/L +   Spray to thoroughly wet all foliage. Minimise contact with desirable species.
                   (Chrysanthemoides monilifera)     except WA                      Pulse®
                                                                                    Penetrant
                                                                                    (10mL/5L)
                   Bridal creeper (Myrisphyllum                 -         5 g/100L -          Apply during mid June to late August. Follow-up applications over at least 2
                   asparagoides)                                                              seasons will be required for complete control. Water volumes of 500-800L/ha
                                                                                              are recommended to minimise the risk of damage to native vegetation.
                   Common bracken (Pteridium                    60 g/ha   10 g/100L -         Spray after full frond expansion. Spray to thoroughly wet all foliage, but not to
                   esculentum)                                                                cause run-off. For boom application - adjust boom height to ensure correct
                                                                                              spray overlap. Avoid spraying when plants are stressed or in conditions of
                                                                                              prolonged dry weather when soils are dry.
                   Crofton weed (Eupatorium                     -         15 g/100L -         Spray to thoroughly wet all foliage, but not to cause run-off. Extra care should
                   adenophorum)                                                               be taken to get good spray penetration when spraying bushes situated in
                                                                                              thickets. Apply to actively growing weeds up to early flowering. Best results
                                                                                              obtained on younger plants. If regrowth occurs, retreat in the subsequent
                                                                                              growth period.
                   Darling pea (Swainsona spp.)                 10 g/ha   -         -         Apply during Spring.
                   Fennel (Foeniculum vulgare)                  -         10 g/100L -         Apply to actively growing plants.
                   Golden dodder (Cuscuta australis)            -         1 g/100L -          Apply as a spot spray to point of run-off. Ensure correct coverage of infested
                                                                                              area. Apply pre-flowering.
                   Gorse (Ulex europaeus)                       -         15 g/100L -         Apply to bushes up to 2m tall. Ensure thorough spray penetration and
                                                                          + Pulse®            coverage of the whole plant.
                                                                          Penetrant
                                                                          (200
                                                                          mL/100L)
                   Great mullein (Verbascum thapsus)            20 g/ha + -         -         Regrowth may occur if growing conditions are not good. Apply during Spring
                                                                Pulse®                        at times of good soil moisture to rosettes before stem elongation.
                                                                Penetrant
                                                                (200mL/
                                                                100L)
                   Hawthorn (Crataegus laevigata)               -         10 g/100L -         Apply when bushes are actively growing. Avoid spraying when bushes are
                                                                                              stressed. Spray to thoroughly wet all foliage, but not to cause run-off.
                   Inkweed (Phytolacca octandra)                -         5 g/100L -          Spray to thoroughly wet all foliage but not to cause run-off.
                   Japanese sunflower (Tihonia                  -         10 g/100L -
                   diversifolia)
                   Kangaroo thorn (Acacia paradoxa)             -                   -         Apply to bushes up to 2.5m high when actively growing.

                   Lantana (Lantana camara)                        -           10 g/100L 2 g/L +       Apply to bushes up to 2m tall. Spray to thoroughly wet all foliage and stems.
                                                                                         Pulse®        Spray should penetrate throughout the bush. Should regrowth occur
                                                                                         Penetrant     retreatment will be necessary.
                                                                                         (10mL/5L)
                   Mistflower (Eupatorium riparium)                -           5 g/100L -              Spray to thoroughly wet all foliage but not to cause run-off. Apply to actively
                                                                                                       growing weeds up to early flowering.
                   Noogoora burr (Xanthium pungens)                -           7.5 g/      -           Apply to actively growing plants. Plants under moisture stress will not be
                                                                               100L                    controlled.
                   Parthenium (Parthenium                          7 g/ha      5 g/100L    -           Handgun - Spray to thoroughly wet all foliage but not to cause runoff.
                   hysterophorus)                                  -                       -           Boom - (Pastures only). Apply up to rosette stage. Spray to thoroughly wet all
                                                                                                       foliage. Adjust boom height to ensure complete overlap.

Page 9

SITUATION          WEEDS                                 STATE                    RATE                   CRITICAL COMMENTS
                                                                       Boom       Handgun     Gas gun
 Native pastures¥, Paterson’s curse/Salvation             All states   15 g/ha                -       Boom - Spray to thoroughly wet all foliage. Adjust boom height to ensure
 rights of way,    Jane (Echium plantagineum)                                                         correct spray overlap.
 commercial and                                                                                       Handgun - Spray to wet all foliage but not to cause run-off.
 industrial areas,                                                                                    WA only - Spray plants at early flowering stage (August - September).
 Cont.             Privet (Ligustrum spp.)                All states -            10 g/100L 1 g/L +   Apply to bushes up to 3m high. Complete foliar spray coverage is essential for
                                                          except WA                         Pulse®    control; partial spray coverage will result in regrowth recovery. DO NOT spray
                                                                                            Penetrant when bushes are stressed.
                                                                                            (10mL/5L)
                    Ragwort (Senecio jacobaea)                         15g/ha     5 g/100L -          Apply to actively growing plants at rosette to cabbage stage.
                    Rubber vine (Cryptostegio                          -          15 g/100L -         Apply to bushes up to 3m tall in height. Apply from October through April
                    grandiflora)                                                                      when bushes are actively growing. Ensure thorough spray coverage of all
                                                                                                      foliage and leaders. Incomplete coverage will result in regrowth.
                    Singapore daisy (Sphagneticola                     -          10 g/100L -         Spray thoroughly to wet all foliage, but not to cause run-off. Minimise contact
                    trilobata)                                                                        with desirable species.
                    Sweet briar (Rosa rubiginosa)                      -          10g/100L 1 g/L +    Apply when bushes are actively growing. Avoid spraying when bushes are
                                                                                            Pulse®    stressed, when leaf fall has commenced or after the end of February.
                                                                                            Penetrant Handgun - Spray to thoroughly wet all foliage, but not to cause run-off.
                                                                                            (10mL/5L) Vic only – Gas gun - Apply to bushes less than 2m high as application to
                                                                                                      bushes in excess of 2m high may produce variable results. Apply with shots of
                                                                                                      25mL of dilute product.
                   Tree-of-heaven (Ailanthus altissima)                -                              Spray to thoroughly wet all foliage, but not to cause run-off.
                   Wait-a-while (Mysore thorn)                         -                    -
                   (Caesalpinia decapetala)
                   Wild turnip (Brassica tournefortii)                 -          5 g/100L    -           Apply to actively growing plants.
¥
  Will damage legumes in pastures

6. NATIVE PASTURES, RIGHTS OF WAY, COMMERCIAL AND INDUSTRIAL AREAS, AND FLOODPLAINS - AERIAL APPLICATION BY HELICOPTER
  CROP                     WEEDS               STATE          RATE          CRITICAL COMMENTS
  Native Pastures¥, rights Blackberry          All states     160 g/ha      Apply when bushes are actively growing. (Tas only: Apply after petal fall. DO NOT apply to
  of way, commercial and                                                    bushes carrying mature fruit). (Vic only: Apply between December and April). Use not less
  industrial areas                                                          than 100L prepared spray/ha.
  Flood Plains             Mimosa pigra                       50 or 60 g/ha Use the higher rate when air temperature exceeds 350C. Apply in at least 60 L/ha of clean
                                                                            water. Use D6 or D8 nozzles with 45 swirl plates pressurised to 210kPa to give a large droplet
                                                                            size. Add a non-ionic surfactant. Apply when plant is actively growing. Avoid spraying when
                                                                            plants are stressed.
¥
  Will damage legumes in pastures
7. PASTURES, FORESTS, COMMERCIAL AND INDUSTRIAL AREAS, RIGHTS OF WAY, DOMESTIC AND PUBLIC SERVICE AREAS: NUFARM ASSOCIATE® AND NUFARM WEEDMASTER®
DUO® NUFARM WEEDMASTER® DST® OR NUFARM CRUCIAL® HERBICIDE
ALL STATES
PLANTING INTERVAL: 1 DAY PER GRAM NUFARM ASSOCIATE® MINIMUM BEFORE PLANTING
 SITUATION          WEEDS                                 RATE – AERIAL OR       RATE – HANDGUN OR CRITICAL COMMENTS
                                                          BOOM                   KNAPSACK
 Pastures and       Blackberry (Rubus spp.)               8.0 L./ha Weedmaster®
                                                                                 400 mL Weedmaster® For Blackberries, apply from flowering until prior to leaf yellowing. Due to
 Forests.           Volunteer pine wildings (suppression  Duo® or 6.2 L/ha
                                                                                 Duo® or 320 mL         widespread picking of Blackberries by the public, it is not recommended
 Planting interval: only)                                 Nufarm Weedmaster®
                                                                                 Nufarm Weedmaster® that the product be applied to bushes bearing mature fruit. Use Pulse
 wait a minimum of                                        DST® or 4.8 L/ha
                                                                                 DST® or 250 mL         Penetrant at the rate of 500mL per 100L water.
 1 day per gram                                           Nufarm Crucial® plus
                                                                                 Nufarm Crucial® plus 3 Application to Pine wildings less than 50cm in height should be controlled
 Nufarm                                                   60 g/ha Nufarm
                                                                                 g Nufarm Associate®    when actively growing.
 Associate® before                                        Associate®
                                                                                 per 100L water
 planting.          Bracken (Pteridium esculentum)        4.0 L/ha Weedmaster  ®
                                                                                                        For Bracken, apply when fronds are fully unfurled but prior to first frosts.
                                                          Duo® or 3.1 L/ha                              For boom application, refer to Boom application section. Use Pulse
 Commercial and                                           Nufarm Weedmaster®                            Penetrant at the rate of 500mL per 100L of water.
 Industrial areas,                                        DST® or 2.4 L/ha                              Use the 60g rate in Spring and the tank mixture in Autumn for best
 Rights of way,                                           Nufarm Crucial® plus                          control option for Bracken.
 Domestic and                                             30 g/ha Nufarm                                DO NOT disturb Bracken for minimum 6 weeks after application.
 public service                                           Associate®
 areas                                                    60 g/ha Nufarm
                                                          Associate®
 DO NOT USE ON Fog grass (Holcuslanatus)                  4.0 L/ha Weedmaster®                          Use Pulse® Penetrant at the rate of 500 mL per 100L of water.
 ALKALINE SOILS Gorse (Ulex europaeus), Lantana           Duo® or 3.1 L/ha                              For Gorse, apply when actively growing at any time of year, except Spring.
                    (Lantana camara),                     Nufarm Weedmaster®                            For Lantana, apply when actively growing. DO NOT apply during periods of
                    St John’s wort (Hypericum perforarum) DST® or 2.4 L/ha                              Summer drought stress.
                    Sorrel (Rumex acetosella)             Nufarm Crucial® plus                          For St John’s wort, apply when actively growing from Spring to Summer.
                    Sweet briar (Rosa rubiginosa)         30 g/ha Nufarm                                For Sweet briar, apply when in full leaf, prior to leaf fall.
                    Topped lavender (Lavandula stoechas) Associate®                                     For Topped lavender, Fog grass and Sorrel, apply when actively growing.
                                                                                                        For Sorrel apply 10-30g when actively growing. DO NOT apply during
                                                                                                        periods of Summer drought stress.

Page 10

8. TOLERANT GRASS PASTURES OR IN A PASTURE RENOVATION - GROUND APPLICATION
 SITUATION              WEEDS                             RATE                  CRITICAL COMMENTS
 ESTABLISHED            Cape tulip: Both one and two leaf 5 g/ha                Apply at bulb exhaustion usually during July/early August. More than one year
 PASTURES               (Homeria spp.)                                          of application may be required to obtain control.
                        Annual clover (Trifolium spp.)                          Apply before flowering.
 TOLERANT GRASS         Dock spp. (Rumex spp.)            5 g/ha - seedlings    Best results when applied in Spring prior to bolting.
 SPECIES                                                  10 g/ha - established
 Perennial phalaris     Doublegee/Spiny emex/Three        5 - 10 g/ha           Apply up to the 6 leaf stage. Use the higher rate on dense populations.
 Perennial cocksfoot    Cornered Jack (Emex australis)
 Stands greater than    Erodium/Storksbill/Wild geranium                        Use the higher rate on dense populations. Spray before flowering.
 one year old           (Erodium spp.)
                        Annual medics (Medicago spp.)     5 g/ha                For best results apply before flowering.
 OR                     Onion grass/Guildford grass       15 g/ha               Apply at bulb exhaustion usually late June/July before the onset of browning
 PASTURE                (Romulea rosea)                                         off caused by fungus. When mixing with glyphosate use 10g/ha.
 RENOVATION             Paterson’s curse/Salvation Jane 10 or 15 g/ha           Apply lower rate to small plants. Apply higher rate before bolting/flowering.
 Use in rundown         (Echium planatagineum)
 pasture to reduce
                        Ragwort (Senecio jacobaea)        15 g/ha               Apply to actively growing plants at the rosette to cabbage stage.
 weed burden before
                        Sorrel (Rumex acetosella)         5 g/ha - seedlings    Best results when applied in Spring prior to seed heads appearing.
 sowing with a
                                                          10 g/ha - established
 pasture in the
                        Soursob (Oxalis pes-caprae)       5 - 10 g/ha           Use the higher rate on dense stands. Spray before flowering for best results.
 following year
                        Wild garlic (Allium vineale)      15 g/ha               Apply at bulb exhaustion usually July to early August. More than one year of
                                                                                application may be required to obtain control.
Note: Always add a non-ionic surfactant (1000 g /L) eg Chemwet 1000 at 200 mL/100L of water (0.2% v/v).
NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER, CONTRARY TO THIS LABEL UNLESS AUTHORISED UNDER APPROPRIATE LEGISLATION.
^
  IN TASMANIA 2, 4-D CAN ONLY BE APPLIED BETWEEN 15TH APRIL AND 15TH SEPTEMBER UNLESS OTHERWISE AUTHORISED BY THE REGISTRAR OF PESTICIDES.

Page 11

Nufarm Associate Herbicide – General Instructions
GENERAL INSTRUCTIONS
Nufarm Associate® is a selective systemic herbicide which is absorbed through the roots and foliage with rapid translocation acting by inhibiting cell division in meristems
thus stopping growth. Some crops are extremely sensitive to low concentrations of this product. See “Sprayer Cleanup” section. Where treatment is delayed or where
weeds are not actively growing due to adverse conditions, results may be slow to appear and weeds may only be stunted or suppressed.
Instructions specific for cereals
With the exception of the preplant weed control recommendations, apply at the early post emergence stage of the crop (Barley, Cereal Rye, Triticale, Wheat: 3 leaf to
before booting) when weeds are small (i.e. no greater than 5cm in height or diameter) and actively growing. Best weed control is obtained when rainfall wets the soil to a
depth of 5 to 7.5cm within 4 weeks of application. Where treatment is delayed or where weeds are not actively growing due to adverse conditions, results may be slow to
appear and weeds may be only stunted or suppressed (eg. Indian hedge mustard). Nufarm Associate® will remain in the soil for a period of time (see Crop Rotation
Recommendations). The persistence of Nufarm Associate® in the soil is dependent on various environmental conditions e.g. soil pH, temperature, soil moisture and
organic matter. Wet, warm, acid soils high in organic matter favour breakdown of Nufarm Associate® in the soil. It should be noted that Nufarm Associate® does not
provide a commercially acceptable level of soil residual weed control. Crops other than wheat, barley, triticale and cereal rye may be extremely sensitive to low
concentrations of Associate residues in the sprayer or in the soil. See “Sprayer Clean-up” and “Crop Rotation Recommendations”.
The recommendation of the addition of Nufarm Associate® to Nufarm Crucial® or Nufarm weedmaster® DST® as a pre-plant knockdown is to enhance the control of certain
broadleaf weeds (e. g. doublegee, sorrel, erodium, clover, medic and soursob) and to help prevent (or at least minimise) the risk of resistant weeds occurring. Its purpose
is not to provide residual control of weeds.
Instructions specific for brush and herbaceous weed control
Apply when bushes/plants are actively growing. Where treatment is delayed or bushes/plants are not actively growing due to adverse conditions (such as a period of
prolonged dry weather) or if partial spray coverage occurs, results may be slow to appear and subsequent regrowth may occur. If regrowth occurs, re-treatment at the
recommended rate is advised. Re-treatment of blackberries should only be undertaken once regrowth has reached 1 m tall - this may not be until 2 years after the initial
application. For control of bushes previously sprayed with other brush control herbicides or for bushes which may have been burned or slashed ensure 2 years has
elapsed. Due to the widespread picking of blackberries by the public, it is recommended that the product is not applied to bushes bearing mature fruit.
Instructions specific for treatment of pasture or pasture renovation
Allow weeds to recover from grazing before application. Docks and sorrel in particular require fresh leaf growth for adequate uptake of chemicals. Legumes will be
removed from pasture if oversprayed with Nufarm Associate®. Some grasses will be damaged in pasture sprayed with the product and biomass production may be
reduced for several months. Nufarm Associate® used on established perennial phalaris and/or established perennial cocksfoot may cause temporary yellowing and some
stunting. Nufarm Associate® can severely damage annual and perennial ryegrass. Nufarm Associate® does not control/damage silvergrass (Vulpia spp.), brome grass
(Bromus spp.) or winter grass (Poa spp.). Sorrel seedlings may germinate after the break in the following year, particularly after cultivation. The ungerminated clover seed
bank is not affected by Nufarm Associate® application. Clover vigour is often increased in the year following application where seed banks are reasonable. The seed set of
clover in the year of application of Nufarm Associate® will be significantly reduced particularly from the winter- spring application. This effect may impact on the clover
seed bank therefore re-sowing may be necessary. Where clover seed banks are high resowing is not necessary. For pasture topping situations a combination of Nufarm
Associate® plus glyphosate can be used, however the Crop Rotation recommendations should be observed. Refer to the Directions of Use section of each product for the
appropriate rate and critical comments for the target weed spectrum.
Crop Safety

Some wheat varieties may be more susceptible to damage from certain tank mixtures, consult your local agronomist or Nufarm representative. Care should be taken if it is intended to apply
Nufarm Associate® in the same season to a crop already treated with another sulfonylurea herbicide as crop damage may occur. Consult your local agronomist or Nufarm
representative.
DO NOT apply other sulfonylurea herbicides in a tank mix with Nufarm Associate® as a pre-plant application. Use of this product on land having a soil pH of 5.5 or less
may result in some crop retardation, particularly if the crop is stressed - see comment in point below.
DO NOT apply to crops that are stressed by any cause (such as severe weather conditions, drought, waterlogging, excessive soil acidity or alkalinity, poor nutrient status,
disease, nematode or insect damage) as crop injury may result. When treatment is followed by severe stress (such as drought, prolonged cold, waterlogging or frosty
conditions) crop yellowing and growth retardation may occur. Crops normally recover without loss in yield. Disease, nematode or insect damage following application
may also result in crop injury.
Spray Preparation
Nufarm Associate® is a water dispersible granule formulation to be mixed with water and applied as a spray. Partially fill the spray tank with water. Using the Nufarm
Associate® measuring cone provided, measure the amount of Nufarm Associate® required for the area to be sprayed. Add the correct amount of Nufarm Associate® to the
spray tank with the agitation system engaged. Top up to the correct volume with water. THE MATERIAL MUST BE KEPT IN SUSPENSION AT ALL TIMES BY CONTINUOUS
AGITATION. When the prepared spray solution has been allowed to stand, thoroughly re-agitate before using. In tank mixes Nufarm Associate® must be in suspension
before adding the companion herbicide or surfactant. For application of Nufarm Associate® in liquid fertiliser, slurry the Nufarm Associate® in water then thoroughly mix
the slurry into the liquid fertiliser. Check compatibility before mixing Nufarm Associate® in fertiliser solutions. DO NOT add a surfactant/wetting agent.
Use of surfactant/wetting agent
Instructions specific for cereals: Always add a non-ionic surfactant (1000 g ac/L) at 100 mL/100L of final spray volume (0.1% volume/volume). The use of spraying oils
is not recommended.
Note: DO NOT add a surfactant/wetting agent when Nufarm Associate® is tank mixed with Nufarm Igran 500 or 900 g/kg diuron WG products.
Instructions specific for brush and herbaceous weed control: If a specific surfactant/wetting agent is not listed in the Directions for Use table, or when mixing
glyphosate use a non-ionic surfactant (1000 g ac/L) at 100mL/100L of final spray volume (ie. 0.1% volume/volume). When an organosilicone penetrant (Pulse®) is
recommended in the Directions for Use table and with all gas gun applications, use 10 mL/5L or 200 mL/100L of final spray volume (ie. 0.2% volume/volume). When a
mineral spray oil (eg. Caltex Sprayplus*) is recommended in the Directions for Use table, use 1 L/100L of final spray volume (ie 1% volume/volume).
Instructions specific for treatment of pasture and pasture renovation: Always add a non-ionic surfactant a (1000 g ac/L) eg. Chemwet 1000 at 200 mL/100L of final
spray volume (0.2% volume/volume).
Boom Spray Application
Use a boom spray properly calibrated to a constant speed and rate of delivery to ensure thorough coverage and a uniform spray pattern. Adjust boom height to ensure
correct spray overlap. Avoid spraying where drift can go onto crops, are likely to be planted to crops and non-target pastures as injury may occur. Avoid overlapping and
shut off spray booms while starting, turning, slowing or stopping as injury to the crop may result.
Cereals: Apply a minimum of 50 L prepared spray/ha.
Pasture: Apply a minimum of 70 L prepared spray/ha.
Other use patterns: Apply in a minimum of 150 L prepared spray/ha. Increase to 200 L prepared spray/ha or more in dense stands.

Page 12

Aerial Application
Avoid spraying in still conditions and in winds likely to cause drift onto adjacent sensitive crops or fallow areas likely to be planted to these crops - see Crop Rotation
Recommendations. Turn off spray boom whilst passing over creeks and dams. DO NOT apply when a temperature air inversion is likely to occur. Use of Micronair
equipment is not recommended due to greater drift potential.
Apply in a minimum of 20L/ha water. Application in a higher water volume of 30 L/ha will improve the reliability of weed efficacy.
Other use patterns: – helicopter only Apply in a minimum of 100 L per ha on Blackberries or 60 L per ha on Mimosa pigra and up to 200 L prepared spray/ha. Higher
water volumes may be necessary to ensure adequate coverage where bushes are large and terrain is steep. Spray with a properly calibrated helicopter using the half
overlap opposite pass technique.
Handgun Application
Pastures and Other use patterns
Spray foliage and canes until wet. Ensure coverage is uniform and complete. Use pressures of 550 – 750 kPa (80 – 100 psi) depending on target species and size of
bush. Use larger nozzles and higher pressures for largest bushes.
Example:
Size No. 4 or 5 spray nozzle: small individual bushes or broadleaf weeds - less than 1 m high
Size No. 5 or 6 spray nozzle: medium sized bushes - 1.2 m high
Size No. 7 or 8 spray nozzle: large bushes 2 – 3 m high or of a large diameter
Note: Use large spray nozzle/high volume for blackberry regrowth. Spray using a wide cone setting as much as possible. Use even, side-by-side spray pattern moving up
from the base to the top of the bush as leaves are wet. For blackberries, do not ignore runners to the side or the top of the bush and ensure spray penetrates larger bushes
to wet foliage and canes.
Gas Gun Application
Pastures and Other use patterns
Apply to ensure good coverage of all foliage is achieved. The use of a suitable marker dye is recommended. eg. Nufarm Spray Marker Dye.
Sprayer Clean-up
Immediately after spraying thoroughly remove all traces of Nufarm Associate® from mixing and spray equipment as follows:
1. Drain tank, then flush tank, boom and hoses with clean water for a minimum of 10 minutes.
2. Fill the tank with clean water then add 300 mL household chlorine bleach (containing 4% chlorine) per 100 L of water. Flush through boom and hoses then allow to
   stand for 15 minutes with agitation engaged, then drain.
3. Repeat step 2.
4. Nozzle and screens should be removed and cleaned separately. To remove traces of chlorine bleach, rinse the tank thoroughly with clean water and flush through
   hoses and boom.
CAUTION: DO NOT use chlorine bleach with ammonia. All traces of liquid fertilizer containing ammonia, ammonium nitrate or ammonium sulphate must be rinsed with
water from the mixing and application equipment before adding chlorine bleach solution. Failure to do so will release a gas with a musty chlorine odour which can cause
eye, nose, throat and lung irritation. DO NOT clean equipment in an enclosed area.
Crop Rotation Recommendations
The use of Nufarm Associate® may prevent early re-establishment of legumes and grasses after treatment. The period that residues persist in the soil will vary according
to site conditions such as climate, soil pH, presence of soil microorganisms, soil temperature, soil moisture and the rate used. Breakdown is fastest in warm wet acid soil
and slower in cold dry alkaline soils. Land previously treated with Nufarm Associate® should not be rotated to crops other than those listed in the tables following.
Tolerance of other crops (grown through to maturity) should be determined on a small scale before sowing into larger areas.
The Nufarm Associate® treated area may be replanted to any of the specified crops after the interval indicated in the following table:
 Soil pHΨ                                   Minimum Recropping Interval
                    10 days              6 weeks            9 months            14 months
 5.6 - 8.5          Wheat                Barley             Chickpeas           Japanese millet
                                         Cereal rye         Faba beans          Maize
                                         Triticale          Linseed             Panorama millet
                                                            Lucerne             White French
                                                            Lupins              millet
                                                            Medics**            Sorghum
                                                            Oats                Soybeans
                                                            Peas                Sunflower
                                                            Canola
                                                            Safflower
                                                            Subterranean**
                                                            Clover
 8.6 and above Tolerance of crops (grown through to maturity) should be determined on a
                    small scale, in the previous season, before sowing into larger areas.
** Involves natural regeneration of subterranean clover and medics.
The Nufarm Associate® treated area may be replanted to any of the specified pasture species after the interval indicated in the following table:
 Soil pHΨ        Pasture Species                   Rate               Minimum           Minimum Re-crop
                                                                      Rainfall          Interval
 5.5 and below Sub Clover(a) and Haifa white       5 g/ha             150 mm            12 weeks
                 clover                            10 g/ha, 15                          20 weeks
                                                   g/ha
                 Cocksfoot spp. and phalaris       5 g/ha, 10 g/ha                      8 weeks
                 spp.                              15 g/ha                              16 weeks
                 Perennial ryegrass spp. and       5 g/ha, 10 g/ha 100 mm               16 weeks
                 fescue spp.                       15 g/ha            150 mm            20 weeks

Page 13

Soil pHΨ           Pasture Species                  Rate              Minimum           Minimum Re-crop
                                                                       Rainfall          Interval
 5.6 - 6.5            Sub Clover(a), Haifa white clover, Bioassay(b)
                      perennial ryegrass spp. and
                      fescue spp.
                      Cocksfoot spp. and phalaris         5, 10 g/ha        175 mm           12 weeks
                      spp.                                15 g/ha           Bioassay(b)
 6.6 and above Bioassay(b)
  (a)
      Varieties: Junee, Karridale, Seaton Park and Trikkala.
  (b)
      Tolerance of pasture species should be determined on a small scale, in the previous season, before sowing into larger areas.
  Ψ Soil pH is to be determined by laboratory analysis using the 1:5 soil water suspension method.

For rates higher than 15 g/ha the following applies:
• For soils with a pH below 7 (1:5 soil: water method) a minimum period of 12 months should elapse before oversowing treated areas with grasses or legumes. It is
  suggested that small areas be oversown 1-2 months prior to the planned time for sowing to check for possible harmful residues.
•      For soils with a pH greater than 7 or if planting any other crop, DO NOT replant without first consulting the local Nufarm representative.
Incompatibility
•      Nufarm Associate® is compatible with the commonly used insecticides chlorpyrifos and omethoate. Some increased temporary crop yellowing may occur when
       Nufarm Associate® is applied as a tank mix with these insecticides.



    DO NOT mix Nufarm Associate® with Achieve and Mataven* 90.
    Notes on Nufarm Associate®/Diclofop methyl based products or Nufarm Associate®/Tristar Mixtures
    •        Nufarm Associate® and diclofop methyl based products or Tristar Advance can be tank mixed, but when this mixture is used, some reduction in grass weed
    control can be expected.
    •        For heavy infestation of grass weeds, control may be inadequate.
    •        Significant reduction in grass weed control should be expected.
    •        Nufarm Associate® and diclofop methyl based products or Tristar Advance are not a recommended mixture because they result in significant reduction in
    grass weed control and/or crop damage.
    •        Consult company representatives for further information or advice.